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Title

1,8-Hydrogen Atom Transfer Promoted by N-Radicals in (1-4)-O-Disaccharide Models

AuthorsLeón, Elisa I. ; Martín, Ángeles ; Pérez-Martín, Inés ; Suárez, Ernesto
KeywordsCarbohydrates
Radical reactions
Hydrogen transfer
Radicals
Issue DateDec-2011
PublisherWiley-VCH
CitationEuropean Journal of Organic Chemistry 36:7339-7345 (2011)
AbstractThe nitrogen-centered radical generated by reaction of an N-sulfonamidate, attached to C-6 of a hexopyranose in a disaccharide model, with (diacetoxyiodo)benzene (DIB) and iodine undergoes a novel regio- and stereoselective intramolecular 1,8-hydrogen atom transfer (HAT) reaction to promote the functionalization of remote positions.
Publisher version (URL)https://doi.org/10.1002/ejoc.201101146
URIhttp://hdl.handle.net/10261/199610
DOI10.1002/ejoc.201101146
ISSN1434-193X
E-ISSN1099-0690
Appears in Collections:(IPNA) Artículos
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