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Title: | Synthesis and catalytic activity of cationic allyl complexes of nickel stabilized by a single N-heterocyclic carbene ligand |
Authors: | Cámpora, Juan CSIC ORCID; Ortiz de la Tabla, Laura; Palma, Pilar CSIC ORCID; Álvarez, Eleuterio CSIC ORCID ; Lahoz, Fernando J. CSIC ORCID; Mereiter, Kurt | Issue Date: | Jun-2006 | Publisher: | American Chemical Society | Citation: | Organometallics 25(14): 3314-3316 (2006) | Abstract: | Cationic allylnickel complexes stabilized by a single N-heterocyclic carbene ligand (NHC) and a labile aquo or acetonitrile ligand have been synthesized by protonation of aryloxide-containing precursors. These complexes catalyze the polymerization of 1,3-butadiene and styrene, mimicking the analogous phosphine-based system. | Description: | 3 pages, 2 figures, 1 scheme.-- Supporting Information Available: http://pubs.acs.org. | Publisher version (URL): | http://dx.doi.org/10.1021/om060439l | URI: | http://hdl.handle.net/10261/19703 | DOI: | 10.1021/om060439l | ISSN: | 0276-7333 |
Appears in Collections: | (IIQ) Artículos (ICMA) Artículos |
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