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Closed Access item Synthesis and catalytic activity of cationic allyl complexes of nickel stabilized by a single N-heterocyclic carbene ligand

Authors:Cámpora, Juan
Ortiz de la Tabla, Laura
Palma Ramírez, Pilar
Álvarez, Eleuterio
Lahoz, Fernando J.
Mereiter, Kurt
Issue Date:Jun-2006
Publisher:American Chemical Society
Citation:Organometallics 25(14): 3314-3316 (2006)
Abstract:Cationic allylnickel complexes stabilized by a single N-heterocyclic carbene ligand (NHC) and a labile aquo or acetonitrile ligand have been synthesized by protonation of aryloxide-containing precursors. These complexes catalyze the polymerization of 1,3-butadiene and styrene, mimicking the analogous phosphine-based system.
Description:3 pages, 2 figures, 1 scheme.-- Supporting Information Available: http://pubs.acs.org.
Publisher version (URL):http://dx.doi.org/10.1021/om060439l
URI:http://hdl.handle.net/10261/19703
ISSN:0276-7333
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Appears in Collections:(IIQ) Artículos
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