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Título : Synthesis and catalytic activity of cationic allyl complexes of nickel stabilized by a single N-heterocyclic carbene ligand
Autor : Cámpora, Juan, Ortiz de la Tabla, Laura, Palma Ramírez, Pilar, Álvarez, Eleuterio, Lahoz, Fernando J., Mereiter, Kurt
Fecha de publicación : Jun-2006
Editor: American Chemical Society
Citación : Organometallics 25(14): 3314-3316 (2006)
Resumen: Cationic allylnickel complexes stabilized by a single N-heterocyclic carbene ligand (NHC) and a labile aquo or acetonitrile ligand have been synthesized by protonation of aryloxide-containing precursors. These complexes catalyze the polymerization of 1,3-butadiene and styrene, mimicking the analogous phosphine-based system.
Descripción : 3 pages, 2 figures, 1 scheme.-- Supporting Information Available:
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ISSN: 0276-7333
DOI: 10.1021/om060439l
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