Please use this identifier to cite or link to this item:
|Statistics||SHARE CORE MendeleyBASE||
|Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL|
Synthesis, structural characterisation and reactions of some vinylgold(I) phosphane complexes.
|Authors:||Mohr, Fabian; Falvello, Larry R.; Laguna, Mariano|
|Citation:||European Journal of Inorganic Chemistry 2006(4): 833-838 (2005)|
|Abstract:||A series of vinylgold(I) complexes [Au(CR=CHR)L] (R = H, Me; L = PPh3, PPh2Me, PPhMe2) were prepared from the reaction of the Grignard reagents [MgBr(CR=CHR)] (R = H, Me) with the gold(I) phosphane complexes [AuCl(L)] (L = PPh3, PPh2Me, PPhMe2) at low temperature. The complexes were characterised by various spectroscopic techniques and, in the case of [Au(CMe=CHMe)(PPh3)], by a single-crystal X-ray structure determination. The gold-carbon bonds of these vinylgold(I) complexes are easily cleaved by acids and, in the presence of potassium permanganate, by species containing acidic protons. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)|
|Description:||6 pages, 2 schemes, 1 figure.|
|Publisher version (URL):||http://dx.doi.org/10.1002/ejic.200500861|
|Appears in Collections:||(ICMA) Artículos|
Files in This Item:
There are no files associated with this item.