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Título: | Determination of the self-association and inter-association equilibrium constants of a carboxylic acid and its mixtures with pyridine derivates |
Autor: | González, Ana I.; Irusta, Silvia CSIC ORCID CVN; Fernández-Berridi, M. J.; Iruin, J. J.; Sierra, Teresa CSIC ORCID ; Oriol, Luis CSIC ORCID | Palabras clave: | H-bonding Supramolecular chemistry Self-association Inter-association equilibrium constants Polycatenar benzoic acid |
Fecha de publicación: | 30-may-2006 | Editor: | Elsevier | Citación: | Vibrational Spectroscopy 41(1): 21-27 (2006) | Resumen: | Infrared spectroscopy has been employed to determine absorptivity coefficients and the self-association equilibrium constant of 3,4,5-tris(dodecyloxy)benzoic acid in cyclohexane. The obtained value is consistent with data reported in bibliography for other similar compounds. The equilibrium constant describing ethylpyridine/carbonyl hydrogen bonds has been determined for mixtures of the above-mentioned acid and two ethylpyridine isomers. The effect of steric hindrance is discussed. | Descripción: | 7 pages, 7 figures, 3 tables. | Versión del editor: | http://dx.doi.org/10.1016/j.vibspec.2005.12.003 | URI: | http://hdl.handle.net/10261/19672 | DOI: | 10.1016/j.vibspec.2005.12.003 | ISSN: | 1359-6462 |
Aparece en las colecciones: | (ICMA) Artículos |
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accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
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