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Liquid crystals from C3-symmetric mesogens for second-order non-linear optics

AuthorsHennrich, Gunther; Omenat, Ana; Asselberghs, Inge; Foerier, Stijn; Clays, Koen; Verbiest, Thierry; Serrano, José Luis
KeywordsBenzene derivatives
Liquid crystals
Materials science
Nonlinear optics
Issue Date24-Mar-2006
CitationAngewandte Chemie International Edition 45(25): 4203-4206 (2006)
AbstractOctopolar tris[(phenyl)ethynyl]benzenes with high second-order nonlinear optical (NLO) activity form discotic liquid-crystalline mesophases whose properties depend on the length of the alkoxy chains. The molecules self-organize in a non-centrosymmetric fashion in the bulk phase which enables the construction of a simple, efficient, NLO device (see picture).
Description4 pages, 3 figures, 2 tables.
Publisher version (URL)http://dx.doi.org/10.1002/anie.200600019
Appears in Collections:(ICMA) Artículos
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