Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/19463
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Checkerboard-ordered pattern of Bi0.5Sr0.5MnO3 low-temperature phase probed by x-ray resonant scattering |
Autor: | Subías, G. CSIC ORCID; García, Joaquín CSIC ORCID; Beran, Premsyl; Sánchez, María Concepción CSIC ORCID; García Muñoz, Josep Lluís CSIC ORCID | Palabras clave: | Bismuth compounds Strontium compounds X-ray scattering Ground states Lattice dynamics Colossal magnetoresistance Jahn-Teller effect |
Fecha de publicación: | may-2006 | Editor: | American Physical Society | Citación: | Physical Review - Section B - Condensed Matter 73(20): 205107.1-205107.13 (2006) | Resumen: | Resonant x-ray scattering (RXS) at the Mn K edge has been used to characterize the low temperature ordered phase of Bi0.5Sr0.5MnO3. Strong resonances were observed for the (030), (050), (05/20), (0 7/2 0), (4 0), and (3 0) reflections as the photon energy is tuned through the Mn K edge. The reported azimuthal and polarization dependence of the resonant intensities indicates that the low temperature phase is described as a checkerboard ordering of two types of Mn sites with different local geometrical structures. One of the sites is anisotropic, a tetragonal distorted oxygen octahedron and the other one is isotropic, a nearly undistorted oxygen octahedron. The distinction of these two Mn sites is accompanied by a displacement of the Mn atoms transverse to the b axis. We conclude that this checkerboard-ordered pattern is a common ground state in half-doped manganites. Intermediate valence states according to fractional charge segregation were deduced for the two nonequivalent Mn atoms, far from the localized Mn3+ and Mn4+ ionic species. Hence, the experimental data discard the ionic model of charge and orbital ordering of localized 3d (or 3d-like) states at the Mn site (or the MnO6 cluster). We suggest a description of the RXS in terms of band structure effects and lattice dynamics. | Descripción: | 13 pages, 12 figures.-- PACS number(s): 75.47.Lx, 61.10.-i, 71.30.+h | Versión del editor: | http://dx.doi.org/10.1103/PhysRevB.73.205107 | URI: | http://hdl.handle.net/10261/19463 | DOI: | 10.1103/PhysRevB.73.205107 | ISSN: | 1098-0121 |
Aparece en las colecciones: | (ICMA) Artículos (ICMAB) Artículos |
Mostrar el registro completo
CORE Recommender
SCOPUSTM
Citations
27
checked on 21-abr-2024
WEB OF SCIENCETM
Citations
26
checked on 23-feb-2024
Page view(s)
406
checked on 23-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.