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Title: | Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(S<sub>p</sub>)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline |
Authors: | Carmona, Daniel CSIC ORCID; Medrano, Roberto; Dobrinovich, Isabel T. CSIC; Lahoz, Fernando J. CSIC ORCID; Ferrer, Joaquina CSIC ORCID; Oro, Luis A. CSIC ORCID | Keywords: | Phosphinoferrocenyloxazoline ligands Rhodium Iridium Ruthenium Osmium Asymmetric catalysis Molecular structures |
Issue Date: | 15-Dec-2006 | Publisher: | Elsevier | Citation: | Journal of Organometallic Chemistry 691(26) 15 December 2006, Pages 5560-5566 | Abstract: | Half-sandwich complexes of formula [(ηn-ring)MClL]PF6 [L = (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline; (ηn-ring)M = (η5-C5Me5)Rh; (η5-C5Me5)Ir; (η6-p-MeC6H4iPr)Ru; (η6-p-MeC6H4iPr)Os] have been prepared and spectroscopically characterised. The molecular structures of the rhodium and iridium compounds have been determined by X-ray crystallography. The related solvate complexes [(η5-C5Me5)ML(Me2CO)]2+ (M = Rh, Ir) are active catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene. | Description: | 6 pages, 3 tables, 2 figures, 1 schema | Publisher version (URL): | http://dx.doi.org/10.1016/j.jorganchem.2006.09.003 | URI: | http://hdl.handle.net/10261/19404 | DOI: | 10.1016/j.jorganchem.2006.09.003 | ISSN: | 1381-1177 |
Appears in Collections: | (ICMA) Artículos |
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