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Title

Synthesis and structure of chiral-at-metal complexes with the ligand (S)-2-[(S<sub>p</sub>)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline

AuthorsCarmona, Daniel CSIC ORCID; Medrano, Roberto; Dobrinovich, Isabel T. CSIC; Lahoz, Fernando J. CSIC ORCID; Ferrer, Joaquina CSIC ORCID; Oro, Luis A. CSIC ORCID
KeywordsPhosphinoferrocenyloxazoline ligands
Rhodium
Iridium
Ruthenium
Osmium
Asymmetric catalysis
Molecular structures
Issue Date15-Dec-2006
PublisherElsevier
CitationJournal of Organometallic Chemistry 691(26) 15 December 2006, Pages 5560-5566
AbstractHalf-sandwich complexes of formula [(ηn-ring)MClL]PF6 [L = (S)-2-[(Sp)-2-(diphenylphosphino)ferrocenyl]-4-isopropyloxazoline; (ηn-ring)M = (η5-C5Me5)Rh; (η5-C5Me5)Ir; (η6-p-MeC6H4iPr)Ru; (η6-p-MeC6H4iPr)Os] have been prepared and spectroscopically characterised. The molecular structures of the rhodium and iridium compounds have been determined by X-ray crystallography. The related solvate complexes [(η5-C5Me5)ML(Me2CO)]2+ (M = Rh, Ir) are active catalysts for the Diels–Alder reaction between methacrolein and cyclopentadiene.
Description6 pages, 3 tables, 2 figures, 1 schema
Publisher version (URL)http://dx.doi.org/10.1016/j.jorganchem.2006.09.003
URIhttp://hdl.handle.net/10261/19404
DOI10.1016/j.jorganchem.2006.09.003
ISSN1381-1177
Appears in Collections:(ICMA) Artículos

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