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dc.contributor.authorMohr, Fabian-
dc.contributor.authorMendía, Aránzazu-
dc.contributor.authorLaguna, Mariano-
dc.date.accessioned2009-12-03T09:07:30Z-
dc.date.available2009-12-03T09:07:30Z-
dc.date.issued2007-05-
dc.identifier.citationEuropean Journal of Inorganic Chemistry (19): 3115-3123 (2007)en_US
dc.identifier.issn1434-1948-
dc.identifier.urihttp://hdl.handle.net/10261/19289-
dc.description9 pages, 2 tables, 8 figures, 5 schemes.en_US
dc.description.abstractAlkylation of 2-hydroxypyridine, 2-pyridinethiol, 2-hydroxy-4-methylquinoline, phthalimide and pyrazole with propargyl bromide gave a series of alkynes in high yield. These alkynes were reacted with the chloroplatinum(II) compounds trans-[PtCl2(PPh3)2] and cis-[PtCl2(dppe)] to afford the respective trans- and cis-bis(alkynyl)platinum(II) complexes, which were characterised by spectroscopic analysis and by X-ray diffraction. The platinum(II) complexes containing the thiopyridyl- and pyrazolyl-substituted alkynes react with 1 or 2 equiv. of [Ag(NO3)(PPh3)] to give dimetallic PtII/AgI complexes.en_US
dc.description.sponsorshipWe wish to thank the Spanish Ministry for Education and Science, Junta de Castilla y León as well as the University of Burgos for generous financial support (grant numbers BQU2005-0899, BU033A06 and 112-541A-487.01).en_US
dc.format.extent259768 bytes-
dc.format.mimetypeapplication/pdf-
dc.language.isoengen_US
dc.publisherWiley-Blackwellen_US
dc.rightsclosedAccessen_US
dc.subjectPlatinumen_US
dc.subjectAlkynesen_US
dc.subjectSilveren_US
dc.subjectDimetallicen_US
dc.subjectCoordination complexesen_US
dc.titlePlatinum(II) alkynyl complexes containing N- and S-propargylated ligands: Synthesis, structures and formation of PtII/AgI coordination compoundsen_US
dc.typeartículoen_US
dc.identifier.doi10.1002/ejic.200700157-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1002/ejic.200700157en_US
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