English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/19171
Share/Impact:
Statistics
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Simple and efficient heterogeneous copper catalysts for enantioselective C−H carbene insertion

AuthorsFraile, José M. ; García, José I. ; Mayoral, José A. ; Roldán, Marta
Issue Date27-Jan-2007
PublisherAmerican Chemical Society
CitationOrg. Lett. 9(4): 731-733 (2007)
AbstractImmobilized box−Cu complexes are able to efficiently catalyze the insertion of a carbene, from methyl phenyldiazoacetate, into C−H bonds of THF, with high enantioselectivity (up to 88% ee). The immobilization not only allows recovery and reuse of the enantioselective catalyst but also provides an improvement in the selectivities from the values obtained in solution, probably due to a confinement effect of the bidimensional support.
Description3 pages, 2 tables, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1021/ol070092y
URIhttp://hdl.handle.net/10261/19171
DOI10.1021/ol070092y
Appears in Collections:(ICMA) Artículos
Files in This Item:
File Description SizeFormat 
accesoRestringido.pdf15,38 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 

Related articles:


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.