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dc.contributor.authorHaro Remón, Marta-
dc.contributor.authorRoss, Daniel J.-
dc.contributor.authorOriol, Luis-
dc.contributor.authorGascón, Ignacio-
dc.contributor.authorCea, Pilar-
dc.contributor.authorLópez, M. Carmen-
dc.contributor.authorAroca, Ricardo F.-
dc.date.accessioned2009-11-30T11:15:32Z-
dc.date.available2009-11-30T11:15:32Z-
dc.date.issued2007-01-04-
dc.identifier.citationLangmuir 23(4): 1804-1809 (2007)en_US
dc.identifier.urihttp://hdl.handle.net/10261/19145-
dc.description.abstractSpectroscopic characterization and fabrication of Langmuir and Langmuir−Blodgett (LB) films of an azopolymer−pyridine (PAzPy) are reported. UV−visible absorption and fluorescence spectra, Fourier transform infrared (FTIR) spectra, and Raman spectra were recorded. The vibrational assignment of the observed spectra is supported by a complete geometry optimization, followed by vibrational frequency and intensity computations of both the trans and cis forms of the monomer (AzPy) using density functional theory at the B3LYP 6-31G(d,p) level of theory. Langmuir monolayers of the polymer (PAzPy) were formed at the water−air interface, and LB films of high quality were formed onto solid substrates. The polymer LB films were investigated by surface-enhanced Raman scattering.en_US
dc.format.extent10752 bytes-
dc.format.mimetypeapplication/octet-stream-
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsclosedAccessen_US
dc.titleSpectroscopic characterization and Langmuir-Blodgett films of a novel azopolymer material.en_US
dc.typeartículoen_US
dc.identifier.doi10.1021/la061491p-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1021/la061491pen_US
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