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dc.contributor.authorEsteruelas, Miguel A.-
dc.contributor.authorHernández, Yohar A.-
dc.contributor.authorLópez, Ana M.-
dc.contributor.authorOliván, Montserrat-
dc.contributor.authorRubio, Lucía-
dc.date.accessioned2009-11-27T11:12:56Z-
dc.date.available2009-11-27T11:12:56Z-
dc.date.issued2008-01-31-
dc.identifier.citationOrganometallics 27(4): 799-802 (2008)en_US
dc.identifier.urihttp://hdl.handle.net/10261/19095-
dc.description4 pages, 4 figures.en_US
dc.description.abstractThe reactivity of the dihydride−acetone complex [OsH2(η5-C5H5)(κ1-OCMe2)(PiPr3)]BF4 (1) toward cinnamaldehyde, isovaleraldehyde, and benzaldehyde has been investigated. In addition to the reduction of the aldehydes, three different reaction patterns have been observed, which depend on the alkenyl, alkyl, and aryl nature of the substituent at the carbonyl group. As a result, the complexes [Os(η5-C5H5)(CO)(η2-PhCHCH2)(PiPr3)]BF4 (2), [Os(η5-C5H5)(CO)2(PiPr3)]BF4 (3), and [OsH(η5-C5H5){C6H4C(O)H}(PiPr3)]BF4 (6) have been isolated and characterized, including the X-ray structure of 2.en_US
dc.description.sponsorshipFinancial support from the MEC of Spain (Projects CTQ2005-00656 and Consolider Ingenio 2010 CSD2007-00006) and Diputación General de Aragón (E35) is acknowledged. Y.A.H. thanks the Spanish MEC for his grant.en_US
dc.format.extent10752 bytes-
dc.format.mimetypeapplication/octet-stream-
dc.language.isoengen_US
dc.publisherAmerican Chemical Societyen_US
dc.rightsclosedAccessen_US
dc.titleReactions of a dihydride-osmium(IV) complex with aldehydes: Influence of the substituent at the carbonyl groupen_US
dc.typeartículoen_US
dc.identifier.doi10.1021/om701075d-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://dx.doi.org/10.1021/om701075den_US
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