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Título: | 1-D arrays of Cu(I)-Schiff base maintained by fourfold phenyl embraces isolating diiodocuprate(I) anions |
Autor: | Amirnasr, Mehdi; Dehno Khalaji, Aliakbar; Falvello, Larry R. CSIC ORCID | Palabras clave: | 1-D array Schiff base Fourfold phenyl embraces Diiodocuprate(I) Supramolecular motif |
Fecha de publicación: | 20-ene-2006 | Editor: | Elsevier | Citación: | Inorganica Chimica Acta 359(2): 713-717 (2006) | Resumen: | The reaction of CuI with the bidentate Schiff base ligand (Phca2-dab) in acetonitrile yields a new mononuclear Cu(I) complex [Cu(Phca2-dab)2][CuI2]. The structure contains cationic moieties of CuI ion coordinated to four N atoms of two Phca2-dab ligands in a distorted tetrahedral fashion and isolated linear diiodocuprate(I) anions. The Phca2-dab ligand adopts a Z,Z configuration. A supramolecular motif that is a one-dimensional array of Phca2-dab embraces formed by the complex has been identified from the crystal packing analysis. The Phca2-dab embrace involves two complexes attracted by two edge-to-face (ef) interactions by the outer phenyl rings of the ligands. | Descripción: | 5 pages, 6 figures, 2 tables, 1 appendix.-- Available online 15 Dec. 2005. | Versión del editor: | http://dx.doi.org/10.1016/j.ica.2005.10.036 | URI: | http://hdl.handle.net/10261/19058 | DOI: | 10.1016/j.ica.2005.10.036 | ISSN: | 0020-1693 |
Aparece en las colecciones: | (ICMA) Artículos |
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