Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/184794COMPARTIR / EXPORTAR:
 SHARE
 CORE
BASE
|
|
| Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
| Título: | Synthesis and oxidationof a paddlewheel-shaped rhodium/antimony complex featuring pyridine-2-thiolate ligands |
Autor: | Wächtler, Erik; Oro, Luis A. CSIC ORCID; Iglesias, Manuel CSIC ORCID; Gerke, Birgit; Pöttgen, Rainer; Gericke, Robert; Wagler, Jörg | Palabras clave: | Antimony Coordination modes Heterobimetallic complexes Oxidation Rhodium |
Fecha de publicación: | 2017 | Editor: | Wiley-VCH | Citación: | Chemistry - A European Journal 23(14): 3447-3454 (2017) | Resumen: | The paddlewheel-shaped complex [Sb(μ-pyS)4 Rh]2 (1) (pyS- = 2-S-C5 H4 N- ) was synthesized from [Rh(pyS)(cod)]2 (cod=1,5-cyclooctadiene) and Sb(pyS)3 . Upon oxidation with ONMe3 , the complex [(μ-O)Sb(μ-pyS)3 Rh(κ2 -pyS)]2 (2) is formed. Both 1 and 2 form dimers and feature short Rh-Sb bonds and bridging pyS ligands. 121 Sb Mössbauer spectro- scopy and computational studies were employed to elucidate the Rh-Sb bonding in 1 and 2. Both covalent (Rh-Sb, X-type Sb ligand) and dative (Rh→Sb, Z-type; Rh←Sb L-type Sb ligand) interactions have to be considered for the description of their bonding situations. | Versión del editor: | https://doi.org/10.1002/chem.201605485 | URI: | http://hdl.handle.net/10261/184794 | DOI: | 10.1002/chem.201605485 | ISSN: | 0947-6539 | E-ISSN: | 1521-3765 |
| Aparece en las colecciones: | (ISQCH) Artículos |
Ficheros en este ítem:
| Fichero | Descripción | Tamaño | Formato | |
|---|---|---|---|---|
| accesoRestringido.pdf | 59,24 kB | Adobe PDF |  Visualizar/Abrir |
CORE Recommender
PubMed Central
Citations
2
checked on 20-abr-2024
SCOPUSTM
Citations
10
checked on 24-abr-2024
WEB OF SCIENCETM
Citations
9
checked on 25-feb-2024
Page view(s)
128
checked on 24-abr-2024
Download(s)
31
checked on 24-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
Artículos relacionados:
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.