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Title

Synthesis of α-Quaternized 2,4-Cyclohexadienones from Propargyl Vinyl Ethers

AuthorsTejedor, David ; Delgado-Hernández, Samuel; Ingold, Mariana; García-Tellado, Fernando
Issue Date6-Oct-2016
PublisherAmerican Chemical Society
CitationJournal of Organic Chemistry 81(20): 10099-10105 (2016)
AbstractA microwave-assisted and base-catalyzed domino manifold to construct 2,4-cyclohexadienone derivatives has been implemented. The domino manifold uses easily accessible tertiary propargyl vinyl ethers bearing a methine group at the homopropargylic position and imidazole as the catalyst to deliver 2,4-cyclohexadienones featuring a key formyl group and a quaternized carbon atom in good yields.
Publisher version (URL)https://doi.org/10.1021/acs.joc.6b02137
URIhttp://hdl.handle.net/10261/183874
DOI10.1021/acs.joc.6b02137
ISSN0022-3263
E-ISSN1520-6904
Appears in Collections:(IPNA) Artículos
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