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Characterization and sintering of alumina-supported palladium catalysts

AuthorsMartín-Luengo, María Ángeles ; Pajares, J. A.; Tejuca, L. G.
Issue Date25-Feb-1984
PublisherWalter de Gruyter
CitationZeitschrift für Physikalische Chemie 140(1): 107-115 (1984)
AbstractA comparative study of methods (H, CO and 0 chemisorption,0 and H titrations and some physical methods) for metal particle size determination in several Pd/Al0 catalysts (metal contents from 0.45to5.26%)was carried out. The results obtained strongly suggest that the H chemisorption in controlled conditions is the most accurate method. Proportions of bridged PdO and PdCO species were determined. It is proposed that the sinterization of these catalysts(in H, high vacuum and H0) between 723 and 973 K takes place by atomic migration. The rate of sintering increased in the series H< highvacuum<H0.This is due to the increased ability of atoms for surface migration caused by the presence of hydroxyl groups.
Publisher version (URL)https://doi.org/10.1524/zpch.1984.140.1.107
Appears in Collections:(ICP) Artículos
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