English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/182508
logo share SHARE logo core CORE   Add this article to your Mendeley library MendeleyBASE

Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:


A quantitative analysis of the dispersion behavior of reduced graphene oxide in solvents

AuthorsAyán Varela, Miguel; Paredes Nachón, Juan Ignacio ; Villar Rodil, Silvia ; Rozada Rodríguez, Rubén ; Martínez Alonso, Amelia ; Díez Tascón, Juan Manuel
Issue Date12-Apr-2014
CitationCarbon 75: 390-400 (2014)
AbstractDetailed knowledge of the dispersion behavior of reduced graphene oxide (RGO) in solvents is important for its practical applications. Such behavior is expected to be different to that observed for pristine graphene, as a result of the chemically heterogeneous structure of RGO (patchwork of pristine and highly oxidized graphene domains). We have investigated the dispersibility of RGO in a wide range of solvents and analyzed the results on the basis of solvent surface energies and Hansen solubility parameters. Although RGO exhibited some features that are characteristic of pristine graphene, its dispersion behavior was dominated by its oxidized graphene domains, with alcohols being commonly the most successful solvents. Estimates of the effective Hansen parameters for RGO derived from the experimental data (δD ≈ 16.9 MPa1/2, δP ≈ 10.7 MPa1/2 and δH ≈ 14.1 MPa1/2) were consistent with this view and afforded the rational design of solvent mixtures that surpassed the best single-component solvents in terms of dispersed amount of RGO. RGO–polymer composites could then be readily prepared in the best performing solvents. Overall, the present results provide a guide to the processing of RGO in the liquid phase with practical utility in the preparation of different graphene-based materials.
Publisher version (URL)https://doi.org/10.1016/j.carbon.2014.04.018
Appears in Collections:(INCAR) Artículos
Files in This Item:
File Description SizeFormat 
Quantitative_analysis_graphene_Ayán.pdf604,14 kBAdobe PDFThumbnail
Quantitative_analysis_graphene_Ayán_SI.pdf126,61 kBAdobe PDFThumbnail
Show full item record
Review this work

Related articles:

WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.