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dc.contributor.authorIehl, Julienes_ES
dc.contributor.authorNguyen, Thi Le Anhes_ES
dc.contributor.authorFrein, Stéphanees_ES
dc.contributor.authorHahn, Uwees_ES
dc.contributor.authorBarberá, Joaquínes_ES
dc.contributor.authorNierengarten, Jean-Françoises_ES
dc.contributor.authorDeschenaux, Robertes_ES
dc.date.accessioned2019-05-21T09:12:35Z-
dc.date.available2019-05-21T09:12:35Z-
dc.date.issued2017-
dc.identifier.citationLiquid Crystals 44(12-13): 1852-1860 (2017)es_ES
dc.identifier.issn0267-8292-
dc.identifier.urihttp://hdl.handle.net/10261/181862-
dc.description.abstractLiquid-crystalline [60]fullerodendrimers were constructed via click chemistry based on the reaction between hexa-adducts of [60]fullerene (C60) bearing 12 azide groups and alkyne-terminated cyanobiphenyl dendrons of first- and second-generation. The structure of all the new compounds was confirmed by IR, UV, 1H and 13C NMR spectroscopies and mass spectrometry. The mesomorphic properties were studied by polarised optical microscopy, differential scanning calorimetry and small-angle X-ray scattering. The hexa-adduct of C60 functionalised with the first-generation dendrons gave rise to the formation of a smectic A phase and a rectangular columnar phase (c2mm symmetry) while the hexa-adduct of C60 decorated with the second-generation dendrons displayed only a rectangular columnar phase (c2mm symmetry). Our results show that the hexa-adduct of C60 is a unique synthetic platform for the design of fullerodendrimers and dendronised materials.es_ES
dc.description.sponsorshipFinancial support from the MINECO (project CTQ2015-70174-P) and Diputación General de Aragón-Fondo Social Europeo (DGA-FSE) (project E04) is gratefully acknowledged. RD thanks the Swiss National Science Foundation [Grant Number 200021-165715] for financial support. JFN and UH gratefully acknowledge financial support from the University of Strasbourg, the CNRS, the International Center for Frontier Research in Chemistry (icFRC) and the LabEx Chimie des Systèmes Complexes.es_ES
dc.language.isoenges_ES
dc.publisherTaylor & Francises_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-70174-Pes_ES
dc.rightsclosedAccesses_ES
dc.subjectHexa-adducts of fullerenees_ES
dc.subjectCyanobiphenyl-based dendrimerses_ES
dc.subjectClick chemistryes_ES
dc.subjectLiquid crystalses_ES
dc.subjectSmectic phaseses_ES
dc.subjectColumnar rectangular phaseses_ES
dc.titleDesigning liquid-crystalline dendronised hexa-adducts of [60]fullerene via click chemistryes_ES
dc.typeartículoes_ES
dc.identifier.doi10.1080/02678292.2017.1336677-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttps://doi.org/10.1080/02678292.2017.1336677es_ES
dc.identifier.e-issn1366-5855-
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderEuropean Commissiones_ES
dc.contributor.funderDiputación General de Aragónes_ES
dc.contributor.funderUniversité de Strasbourges_ES
dc.contributor.funderSwiss National Science Foundationes_ES
dc.contributor.funderCentre National de la Recherche Scientifique (France)es_ES
dc.relation.csices_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003768es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004794es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000780es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.openairetypeartículo-
item.cerifentitytypePublications-
item.languageiso639-1en-
item.grantfulltextnone-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.fulltextNo Fulltext-
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