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| Título: | Microbial transformation of the diterpene 7-epi-foliol by Fusarium fujikuroi |
Autor: | Fraga, Braulio M. CSIC; Bressa, Carlo CSIC ORCID; González, Pedro; Guillermo, Ricardo CSIC | Palabras clave: | Diterpenes 7-epi-Foliol 18-Oxo-7-epi-foliol Ent-Kaur-16-enes Fusarium fujikuroi Biotransformations |
Fecha de publicación: | 2014 | Editor: | Sage Publications | Citación: | Natural product communications 9(8): 1061-1063 (2014) | Resumen: | The incubation of 3,7,18-trihydroxy-ent-kaur-16-ene (7-epi-foliol) with the fungus Fusarium fujikuroi gave 3,7,18-trihydroxy-ent-kaur-16-en-18-al as the sole product. The biotransformation of other 7- or 7-hydroxy derivatives had led to the oxidation of C-19, which is a main step in the biosynthesis of gibberellins and kaurenolides. Now, the presence of the 3-hydroxyl impedes that oxidation, which is directed to the adjacent C-18 hydroxymethyl forming the corresponding aldehyde. | URI: | http://hdl.handle.net/10261/180336 | Identificadores: | issn: 1934-578X e-issn: 1555-9475 |
| Aparece en las colecciones: | (IPNA) Artículos |
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| Microbial_Fraga_2014.pdf | 308,12 kB | Adobe PDF |  Visualizar/Abrir |
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