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Title

Synthesis of chiral sulfinamido-sulfonamides and their evaluation as ligands for the enantioselective ethylation of aldehydes

AuthorsViso, Alma ; Fernández de la Pradilla, Roberto ; Ureña, Mercedes
KeywordsSulfinamido-sulfonamide ligands
Aldehyde
Diethylzinc
Ti(O(i)Pr)4
Issue Date24-Feb-2009
PublisherElsevier
CitationTetrahedron 65(18): 3757-3766 (2009)
AbstractA family of chiral sulfinamido-sulfonamide ligands have been synthesized from sulfinimines and has been evaluated as ligands for the enantioselective addition of diethylzinc to aldehydes with Ti(O(i)Pr)4. The structure of these diamino compounds has been systematically modified to optimize the results.
Description10 pages, 2 figures, 2 tables.-- Printed version published May 2, 2009.
Publisher version (URL)http://dx.doi.org/10.1016/j.tet.2009.02.033
URIhttp://hdl.handle.net/10261/17947
DOI10.1016/j.tet.2009.02.033
ISSN0040-4020
Appears in Collections:(IQOG) Artículos
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