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dc.contributor.authorMonterde, Cristina-
dc.contributor.authorNavarro, Rodrigo-
dc.contributor.authorIglesias, Marta-
dc.contributor.authorSánchez, Félix-
dc.date.accessioned2019-02-19T09:32:33Z-
dc.date.available2019-02-19T09:32:33Z-
dc.date.issued2019-
dc.identifierdoi: 10.1021/acsami.8b18053-
dc.identifierissn: 1944-8244-
dc.identifiere-issn: 1944-8252-
dc.identifier.citationACS Applied Materials and Interfaces 11: 3459-3465 (2019)-
dc.identifier.urihttp://hdl.handle.net/10261/176357-
dc.description.abstractA porous polymer containing a fluorophenylphenanthroimidazole core was easily prepared via one-pot Suzuki-Miyaura cross-coupling reactions under microwave heating. These new metal-free polymers have demonstrated heterogeneous photocatalytic activity toward aza-Henry reaction with reasonable recyclability. Their preparation require a minimal workup to build porous networks with control over the apparent surface area and pore volume from suitable molecular building blocks containing 2-(1H-phenanthro[9,10-d]imidazol-2-yl)-3,5-difluorophenol (PhIm-2F), as rigid and multitopic node, which afforded a conjugated porous polymer (CPP-PhIm-2F). A series of fluorinated ligands have shown their capability in the preparation of soluble and supported cationic Ru(bpy)(F-phenanthroimidazole) complexes by reaction with Ru(bpy)Cl and demonstrating a beneficial effect of two fluorine atoms on the photocatalytic effect.-
dc.description.sponsorshipAuthors acknowledge MINECO of Spain (Projects MAT2014- 52085-C2-2-P, MAT2017-82288-C2-2-P) and the Comunidad de Madrid S2013/MIT-2740 project for financial support.-
dc.publisherAmerican Chemical Society-
dc.relationMINECO/ICTI2013-2016/MAT2014- 52085-C2-2-P-
dc.relationMICIU/ICTI2017-2020/MAT2017-82288-C2-2-P-
dc.rightsclosedAccess-
dc.subjectHeterogenized catalyst-
dc.subjectAza-Henry-
dc.subjectConjugated polymer-
dc.subjectRuthenium photocatalyst-
dc.subjectPorous organic polymer-
dc.subjectPhenanthroimidazole-
dc.subjectPhotocatalysis-
dc.titleFluorine-Phenanthroimidazole Porous Organic Polymer: Efficient Microwave Synthesis and Photocatalytic Activity-
dc.typeArtículo-
dc.relation.publisherversionhttp://dx.doi.org/10.1021/acsami.8b18053-
dc.date.updated2019-02-19T09:32:33Z-
dc.description.versionPeer Reviewed-
dc.language.rfc3066eng-
dc.contributor.funderMinisterio de Economía, Industria y Competitividad (España)-
dc.contributor.funderMinisterio de Ciencia, Innovación y Universidades (España)-
dc.contributor.funderComunidad de Madrid-
dc.relation.csic-
dc.identifier.funderhttp://dx.doi.org/10.13039/100012818es_ES
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