Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/17583
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.author | Carrau, Reyes | en_US |
dc.contributor.author | Hernández, Rosendo | en_US |
dc.contributor.author | Suárez, Ernesto | en_US |
dc.contributor.author | Betancor, Carmen | en_US |
dc.date.accessioned | 2009-10-09T09:31:44Z | - |
dc.date.available | 2009-10-09T09:31:44Z | - |
dc.date.issued | 1987 | en_US |
dc.identifier.citation | Journal of the Chemical Society - Perkin Transactions 1987: 937-943 (1987) | en_US |
dc.identifier.issn | 1472-7781 | - |
dc.identifier.uri | http://hdl.handle.net/10261/17583 | - |
dc.description | 7 pages, 1 table, 2 schemes. | - |
dc.description.abstract | Photolysis of 3β-methoxymethoxy-5α-cholestan-6β-ylcyanamide (6), 29-methoxyfriedelan-3β-yl-cyanamide (15), (22R,25R)-5α-furostan-26-ylcyanamide (23), 8α,12-(12R/12S)-epoxylabdan-15-ylcyanamides, (32) and (33), in the presence of iodine and lead tetra-acetate leads to neutral cyanimyl radicals which undergo intramolecular hydrogen abstraction to produce N-cyanoepimino compounds. Better results are obtained with the system iodine and diacetoxyiodobenzene. The starting cyanamides have been prepared by reduction of the oximes (3) and (13) and of the amides (20), (28), and (29), respectively, with lithium aluminium hydride followed by cyanation with cyanogen bromide or with sodium cyanate and subsequent dehydration of the urea derivative with methanesulphonyl chloride. | - |
dc.description.sponsorship | This work was supported by the Investigation Programme of the Comisión Asesora de Investigación Científica y Técnica. R.C. expresses her gratitude to the Excmo. Cabildo Insular de Tenerife for a fellowship. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 1364636 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Royal Society of Chemistry (UK) | - |
dc.rights | closedAccess | en_US |
dc.title | Intramolecular functionalization of N-cyanamide radicals: synthesis of 1,4-and 1,5-N-cyanoepimino compounds | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1039/P19870000937 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1039/P19870000937 | - |
dc.contributor.funder | Comisión Asesora de Investigación Científica y Técnica, CAICYT (España) | - |
dc.contributor.funder | Gobierno de Canarias | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100007272 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | none | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | No Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (IPNA) Artículos |
CORE Recommender
WEB OF SCIENCETM
Citations
50
checked on 27-feb-2024
Page view(s)
379
checked on 19-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.