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Nitroamine radicals as intermediates in the functionalization of non-activated carbon atoms

AuthorsHernández, Rosendo ; Rivera, Augusto; Salazar, José A.; Suárez, Ernesto
Issue Date1980
PublisherRoyal Society of Chemistry (UK)
CitationChemical Communications 1980(20): 958-959 (1980)
AbstractPhotolysis of N-iodonitroamines generated in situ from the steroidal nitroamines 6β-nitroamino-5α-cholestan-3β-ol acetate, 6β-nitroamino-5α-cholestane-3β,5α-diol diacetate, and 20R-nitroaminopregn-5-en-3-ol acetate removes hydrogen atoms from the Me-18 and Me-19 groups to give 6β-,19-N-nitroepinino-5α-cholestan-3β-ol acetate, 6β,19-N-nitroepinino-5α-cholestane-3β5α-diol diacetate, and 18,20R-N-nitroepiminopregn-5-en-3β-ol acetate.
Publisher version (URL)http://dx.doi.org/10.1039/C39800000958
Appears in Collections:(IPNA) Artículos
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