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Crystal structure and characterization of a novel layered copper-lithium phosphonate with antiferromagnetic intrachain Cu(II)···Cu(II) interactions

AuthorsAbdelbaky, Mohammed S. M.; Amghouz, Z.; Martínez-Blanco, David; García-Granda, Santiago ; García, José R.
KeywordsMetal phosphonate
Issue Date2017
CitationJournal of Solid State Chemistry 248: 61-67 (2017)
AbstractNovel metal phosphonate [CuLi(PPA)] [H3PPA=3-phosphonopropionic acid] was synthesized hydrothermally and characterized by single-crystal X-ray diffraction, powder X-ray diffraction, scanning electron microscopy, infrared spectroscopy, and thermogravimetric analysis. It crystallizes in the space group C2/c, with cell parameters a=21.617(2) Å, b=4.9269(2) Å, c=14.342(1) Å, β=132.3(2)°, and Z=8. Its framework is built up from a main trimer, acting as a secondary building unit (SBU), which is formed by vertex-shared between two {LiO4} and one {Cu(1)O4} polyhedra. These units repeat along b-axis forming infinite inorganic chains, these chains are in turn cross-linked by corner sharing with {Cu(2)O4} polyhedra to produce inorganic layers lying in the bc-plane. The neighboring layers are connected through the PPA ligand, leading to a 3D pillared-layered structure. The topological analysis reveals that the compound exhibits 3,4,10-c net. Finally, magnetic susceptibility measurement of this compound over the temperature range of 2–300 K reveals the occurrence of weak antiferromagnetic intrachain interactions.
Identifiersdoi: 10.1016/j.jssc.2017.01.020
issn: 0022-4596
Appears in Collections:(CINN) Artículos
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