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Title: β-Fragmentation of alkoxy radicals. An approach to the synthesis of ring a of vernolepin
Authors: Francisco, Cosme G., Freire, Raimundo, Rodríguez Morales, María S., Suárez, Ernesto
Issue Date: 1987
Publisher: Elsevier
Abstract: A model of ring A of vernolepin is synthesized by 1,4-fragmentation of γ-thiyl and γ-stannyl alkoxy-radicals, generated by photolysis of the corresponding δ-lactols (4) and (5) in the presence of iodosobenzene diacetate and iodine. It should be pointed out that the δ-lactone ring and the angular vinyl group are introduced in one step.
Description: 4 pages, 1 table, 2 schemes.
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ISSN: 0040-4039
???metadata.dc.identifier.doi???: 10.1016/S0040-4039(00)95523-0
Citation: Tetrahedron Letters 28(29): 3397-3400 (1987)
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