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Closed Access item Fragmentation of peroxyhemiacetals. Stereoselective synthesis of 1,2-dioxolanes

Authors:Hernández, Rosendo
Velázquez, Silvia M.
Suárez, Ernesto
Prangé, Thierry
Issue Date:26-Aug-1996
Publisher:Elsevier
Citation:Tetrahedron Letters 37(35): 6409-6412 (1996)
Abstract:A new and efficient approach to the synthesis of 1,2-dioxolanes by β-fragmentation of alkoxy radicals from readily available peroxyhemiacetals, under mild conditions, is described. The radical reaction proceeds in a diastereoselective manner providing a sole 1,2-dioxolane.
Description:4 pages, 1 figure, 3 schemes.
Publisher version (URL):http://dx.doi.org/10.1016/0040-4039(96)01360-3
URI:http://hdl.handle.net/10261/17243
ISSN:0040-4039
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Appears in Collections:(IPNA) Artículos

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