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Cis- and trans-fused Di-tetrahydropyrans by rearrangement of steroidal spiroacetals

AuthorsDorta, Rosa L. ; Freire, Raimundo ; Martín, Ángeles ; Suárez, Ernesto ; Prangé, Thierry
Issue Date2-Oct-1995
CitationTetrahedron Letters 36(40): 7309-7312 (1995)
AbstractA new method for the synthesis of steroidal cis- and trans-fused di-tetrahydropyrans (1,6-dioxadecalins) by reduction with DIBAH of derivatives of 1,6-dioxaspiro[4,5]decan-10-yl methanesulfonate is described.
Description4 pages, 2 figures, 3 schemes.
Publisher version (URL)http://dx.doi.org/10.1016/0040-4039(95)01472-T
Appears in Collections:(IPNA) Artículos
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