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Interaction of an imidazolium-2-amidinate (NHC-CDI) zwitterion with zinc dichloride in dichloromethane: role as ligands and C-Cl activation promoters

AuthorsSánchez-Roa, David; Santiago, Tomás G.; Fernández-Millán, Maria; Cuenca, Tomás; Palma, Pilar ; Cámpora, Juan ; Mosquera, Marta E.G.
Issue DateOct-2018
PublisherRoyal Society of Chemistry (Great Britain)
CitationChemical Communications, 54, 12586-12589 (2018)
AbstractAdducts of imidazolium carbenes and carbodiimides (NHC-CDI) are emerging as a new class of thermally stable and modular zwitterions with many potential applications. Our study of the interaction of a representative NHC-CDI zwitterion with ZnCl2 in dichloromethane led to the serendipitous discovery of a highly selective, double activation of dichloromethane C–Cl bonds
Publisher version (URL)https://doi.org/10.1039/C8CC07661H
Appears in Collections:(IIQ) Artículos
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