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Influence of rotation on the vibrational predissociation of the van der Waals molecule HeI2

AuthorsBeswick J. Alberto; Delgado Barrio, Gerardo
Issue DateOct-1980
PublisherAmerican Institute of Physics
CitationJournal of Chemical Physics 73: 3653-3659 (1980)
AbstractWe apply a rotational decoupling scheme related to the infinite order sudden approximation to treat vibrational predissociation of the triatomic van der Waals molecule HeI2. The potential surface is described by the sum of three Morse potentials between individual bonds. The total rate for vibrational predissociation as a function of vibrational excitation is compared with the results obtained for the colinear and T-shaped models. Final rotational distributions for the I2 fragment are also obtained. © 1980 American Institute of Physics.
Description7 pags., 5 figs.
Publisher version (URL)https://doi.org/10.1063/1.440592
Identifiersdoi: 10.1063/1.440592
issn: 0021-9606
Appears in Collections:(CFMAC-IEM) Artículos
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