English   español  
Please use this identifier to cite or link to this item: http://hdl.handle.net/10261/16989
Share/Impact:
Statistics
logo share SHARE   Add this article to your Mendeley library MendeleyBASE
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL
Exportar a otros formatos:

Title

Reacción de dobles enlaces con NO2Na-AcOH en presencia de F3B I. Derivados del colestano

AuthorsGonzález, Antonio G.; Freire, Raimundo ; García-Estrada, M. G.; Salazar, José A.; Suárez, Ernesto
Issue DateSep-1972
PublisherReal Sociedad Española de Física y Química
Consejo Superior de Investigaciones Científicas (España)
CitationAnales de Química 68(9-10): 1145-1152 (1972)
AbstractThe reaction of cholesterol with NaNO2/BF3 in AcOH yields its 5α-acetyl-6-nitrimine derivative, which is easily transformed into cholestan-3β,5α-diol-6-one 5-acetate. A similar treatment of cholest-4-ene gives the acetates of cholestan-5α-ol-4-one, cholestan-5β-ol-4-one and of the corresponding 4-nitrimine derivatives. This represents a new method for obtaining α-acetyl- and α,β-unsaturated ketones.
Description8 páginas, 1 tabla, 3 esquemas.
URIhttp://hdl.handle.net/10261/16989
ISSN0034-088X
Appears in Collections:(IPNA) Artículos
Files in This Item:
File Description SizeFormat 
ANQ-1972-68-1145.pdf759,12 kBAdobe PDFThumbnail
View/Open
Show full item record
Review this work
 


WARNING: Items in Digital.CSIC are protected by copyright, with all rights reserved, unless otherwise indicated.