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Title: | Fragmentation of alkoxy radicals: Tandem β-fragmentation-cycloperoxyiodination reaction |
Authors: | Boto, Alicia CSIC ORCID ; Betancor, Carmen; Prangé, Thierry; Suárez, Ernesto CSIC ORCID | Issue Date: | 27-Oct-1992 | Publisher: | Elsevier | Citation: | Tetrahedron Letters 33(44): 6687-6690 (1992) | Abstract: | A new tandem β-fragmentation-cycloperoxyiodination reaction is observed when a homoallylic alcohol is irradiated with visible light in the presence of (diacetoxyiodo)benzene and iodine under an atmosphere of oxygen. A synthetically interesting epidioxyiodide medium-sized ketone is obtained by this method. | Description: | 4 pages, 1 figure, 1 table, 2 schemes. | Publisher version (URL): | http://dx.doi.org/10.1016/S0040-4039(00)61020-1 | URI: | http://hdl.handle.net/10261/16969 | DOI: | 10.1016/S0040-4039(00)61020-1 | ISSN: | 0040-4039 |
Appears in Collections: | (IPNA) Artículos |
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