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Título: | Fragmentation of carbohydrate anomeric alkoxy radicals. Tandem β-fragmentation-cyclization of alcohols |
Autor: | Armas, Pedro de CSIC; Francisco, Cosme G. CSIC; Suárez, Ernesto CSIC ORCID | Fecha de publicación: | sep-1993 | Editor: | American Chemical Society | Citación: | Journal of the American Chemical Society 115(19): 8865-8866 (1993) | Resumen: | In recent years there has been a growing interest in carbohydrates as synthetic precursors to enantiomerically pure bioactive molecules because of their well-defined stereochemistry, highly functionalized nature, and distinct reactivities of the hydroxyl groups. We consider worthwhile a general procedure to obtain cyclic carbohydrates, even those not easily accessible by other routes, with a masked hydroxy aldehyde, the elaboration of which may be conveniently timed and whose functionalities would each be eligible for further elaboration. | Descripción: | 2 pages, 1 table, 1 scheme. | Versión del editor: | http://dx.doi.org/10.1021/ja00072a060 | URI: | http://hdl.handle.net/10261/16962 | DOI: | 10.1021/ja00072a060 | ISSN: | 0002-7863 |
Aparece en las colecciones: | (IPNA) Artículos |
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