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Title

Fragmentation of carbohydrate anomeric alkoxy radicals. Tandem β-fragmentation-cyclization of alcohols

AuthorsArmas, Pedro de ; Francisco, Cosme G. ; Suárez, Ernesto
Issue DateSep-1993
PublisherAmerican Chemical Society
CitationJournal of the American Chemical Society 115(19): 8865-8866 (1993)
AbstractIn recent years there has been a growing interest in carbohydrates as synthetic precursors to enantiomerically pure bioactive molecules because of their well-defined stereochemistry, highly functionalized nature, and distinct reactivities of the hydroxyl groups. We consider worthwhile a general procedure to obtain cyclic carbohydrates, even those not easily accessible by other routes, with a masked hydroxy aldehyde, the elaboration of which may be conveniently timed and whose functionalities would each be eligible for further elaboration.
Description2 pages, 1 table, 1 scheme.
Publisher version (URL)http://dx.doi.org/10.1021/ja00072a060
URIhttp://hdl.handle.net/10261/16962
DOI10.1021/ja00072a060
ISSN0002-7863
Appears in Collections:(IPNA) Artículos
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