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Heteroatom framework distribution and layer charge of sodium Taeniolite

AuthorsPerdigón, Ana C,; Pesquera, Carmen; Cota, Agustín; Osuna, Francisco J. ; Pavón, Esperanza ; Alba, María D.
Issue Date2018
CitationApplied Clay Science 158: 246- 251 (2018)
AbstractThe most advanced applications of clays depend crucially on their hydration state and swelling is probably the most important feature of expandable 2:1 layered silicate. Sodium Taeniolite, Na-TAE, a swelling trioctahedral fluormica, has been synthesized and studied using thermogravimetric analysis, X-ray diffraction, scanning electron microscopy and infrared and solid state NMR spectroscopies. The results indicated the formation of a swelling 2:1 phyllosilicate with actual layer charge lower than the nominal one. Herein, a new heteroatom distribution and more accurate composition could be deduced.
Identifiersdoi: 10.1016/j.clay.2018.03.036
issn: 0169-1317
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