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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/16841
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dc.contributor.authorTrillo, Beatriz-
dc.contributor.authorLópez, Fernando-
dc.contributor.authorMontserrat, Sergi-
dc.contributor.authorUjaque, Gregori-
dc.contributor.authorCastedo, Luis-
dc.contributor.authorLledós, Agustí-
dc.contributor.authorMascareñas, José L.-
dc.date.accessioned2009-09-10T11:45:54Z-
dc.date.available2009-09-10T11:45:54Z-
dc.date.issued2009-02-19-
dc.identifier.citationA European Journal Chemistry - A European Journal Volume 15 Issue 14, Pages 3336 -en_US
dc.identifier.urihttp://hdl.handle.net/10261/16841-
dc.description.abstractEfficient at room temperature: The Au complex generated in situ from [(IPr)AuCl] and AgSbF6 promotes the [4C+3C] intramolecular cycloaddition of allenes and dienes at room temperature, and in a particularly efficient and versatile manner. A DFT study on dimethylallenyl precursors agreed with the formation and cycloaddition of a metal-allyl cation intermediate, and points to the 1,2-hydride shift as the key rate-limiting step.en_US
dc.description.sponsorshipThis work was supported by the Spanish MEC [SAF2007-61015, CTQ2008-06866-CO2-01, and Consolider-Ingenio 2010 (CSD2007-00006)], Xunta de Galicia (GRC2006/132 and PGIDIT06PXIB209126PR), and Generalitat de Catalunya (2005SGR00715). B.T., S.M., and F.L. thank the Spanish MICINN for each FPU fellowship and a Ramon y Cajal contract, respectively. We thank Johnson-Matthey for a gift of metals. We thank Isaac Alonso for carrying out some supporting experiments.en_US
dc.format.extent24064 bytes-
dc.format.mimetypeapplication/msword-
dc.language.isoengen_US
dc.publisherWiley-VCHen_US
dc.rightsclosedAccessen_US
dc.subjectAllenesen_US
dc.subjectCarbocyclesen_US
dc.subjectCycloadditionen_US
dc.subjectDensity functional calculationsen_US
dc.subjectGolden_US
dc.subjectHomogeneous catalysisen_US
dc.titleGold-Catalyzed [4C+3C] Intramolecular Cycloaddition of Allenedienes: Synthetic Potential and Mechanistic Implicationsen_US
dc.typeartículoen_US
dc.identifier.doi10.1002/chem.200900164-
dc.description.peerreviewedPeer revieweden_US
dc.relation.publisherversionhttp://www3.interscience.wiley.com/journal/122210085/abstract?CRETRY=1&SRETRY=0en_US
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
item.languageiso639-1en-
item.fulltextNo Fulltext-
item.openairecristypehttp://purl.org/coar/resource_type/c_18cf-
item.cerifentitytypePublications-
item.grantfulltextnone-
item.openairetypeartículo-
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