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Campo DC | Valor | Lengua/Idioma |
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dc.contributor.author | Freire, Raimundo | en_US |
dc.contributor.author | Martín, Ángeles | en_US |
dc.contributor.author | Pérez-Martín, Inés | en_US |
dc.contributor.author | Suárez, Ernesto | - |
dc.date.accessioned | 2009-09-09T07:25:37Z | - |
dc.date.available | 2009-09-09T07:25:37Z | - |
dc.date.issued | 2002-06-09 | en_US |
dc.identifier.citation | Tetrahedron Letters 43(29): 5113-5116 (2002) | en_US |
dc.identifier.issn | 0040-4039 | - |
dc.identifier.uri | http://hdl.handle.net/10261/16767 | - |
dc.description | 4 pages, 1 table, 2 schemes.-- Printed version published Jul 15, 2002. | - |
dc.description.abstract | The preparation of 1-oxa-6-azaspiro[4.4]nonane, 1-oxa-6-azaspiro[4.5]decane, 6-oxa-1-azaspiro[4.5]decane, and 1-oxa-7-azaspiro[5.5]undecane ring systems by 1,6- and 1,7-hydrogen atom transfer promoted by phosphoramidyl radicals in carbohydrate models is described. The N-radicals are generated by reaction of dibenzyl phosphoramidate derivatives of C-glycosides with (diacetoxyiodo)benzene and iodine through an homolytic fragmentation of iodoamide intermediates. | - |
dc.description.sponsorship | This work was supported by the Investigation Programmes no. BQU2000-0650 and BQU2001-1665 of the Dirección General de Investigación Cientı́fica y Técnica, Spain. I.P.-M. thanks the I3P-CSIC Programme for a fellowship. | - |
dc.format.extent | 2373 bytes | - |
dc.format.extent | 146941 bytes | - |
dc.format.mimetype | text/plain | - |
dc.format.mimetype | application/pdf | - |
dc.language.iso | eng | en_US |
dc.publisher | Elsevier | - |
dc.rights | openAccess | en_EN |
dc.title | Synthesis of oxa-aza spirobicycles by intramolecular hydrogen abstraction promoted by N-radicals in carbohydrate systems | en_US |
dc.type | artículo | en_US |
dc.identifier.doi | 10.1016/S0040-4039(02)00983-8 | - |
dc.relation.publisherversion | http://dx.doi.org/10.1016/S0040-4039(02)00983-8 | - |
dc.contributor.funder | Consejo Superior de Investigaciones Científicas (España) | - |
dc.contributor.funder | Dirección General de Investigación Científica y Técnica, DGICT (España) | - |
dc.identifier.funder | http://dx.doi.org/10.13039/501100003339 | es_ES |
dc.identifier.funder | http://dx.doi.org/10.13039/501100008737 | es_ES |
dc.type.coar | http://purl.org/coar/resource_type/c_6501 | es_ES |
item.openairetype | artículo | - |
item.grantfulltext | open | - |
item.cerifentitytype | Publications | - |
item.openairecristype | http://purl.org/coar/resource_type/c_18cf | - |
item.fulltext | With Fulltext | - |
item.languageiso639-1 | en | - |
Aparece en las colecciones: | (IPNA) Artículos |
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TL 2002, 43, 5113.pdf | Artículo principal | 3,33 MB | Adobe PDF | Visualizar/Abrir |
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