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| Título: | Redox-assisted osmium-promoted C–C bond activation of alkylnitriles |
Autor: | Babón, Juan C. CSIC ORCID; Esteruelas, Miguel A. CSIC ORCID; Fernández, Israel; López, Ana M. CSIC ORCID; Oñate, Enrique CSIC ORCID | Fecha de publicación: | 25-jun-2018 | Editor: | American Chemical Society | Citación: | Organometallics 37(13): 2014–2017 (2018) | Resumen: | The redox-assisted C(sp)–C(sp3) bond activation of alkylnitriles coordinated to osmium(II) dihydride fragments has been performed with an osmium(VI) polyhydride to liberate alkanes and generate dinuclear complexes formed by two osmium(IV) polyhydride moieties linked by only one CN bridge. In addition, the bonding situation in these novel dinuclear species has been computationally studied. | Versión del editor: | http://dx.doi.org/10.1021/acs.organomet.8b00326 | URI: | http://hdl.handle.net/10261/167440 | DOI: | 10.1021/acs.organomet.8b00326 | ISSN: | 0276-7333 | E-ISSN: | 1520-6041 |
| Aparece en las colecciones: | (ISQCH) Artículos |
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| Revised _nitriles_JCBabon.pdf | 751,44 kB | Adobe PDF |  Visualizar/Abrir |
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