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Título: | Synthesis, Structure and Anion Sensing Properties of a Dicationic Bis(imidazolium)-Based Cyclophane |
Autor: | Sabater, Paula; Zapata, Fabiola; Caballero, Antonio CSIC ORCID; Alkorta, Ibon CSIC ORCID ; Ramírez de Arellano, Carmen; Elguero, José CSIC ORCID; Molina, Pedro | Palabras clave: | Cyclophane Sensor Imidazolium Hydrogen bonds Anions |
Fecha de publicación: | 2018 | Editor: | ChemPubSoc Europe | Citación: | ChemistrySelect 3: 3855-3859 (2018) | Resumen: | The preparation and sensing properties of a tetracyclic cyclophane receptor containing two imidazolium rings as anion binding sites and two fluorene rings as fluorescent signaling units, are reported. The receptor behaves as a selective fluorescent chemosensor molecule for inorganic phosphates. H-NMR spectroscopical data clearly indicate the simultaneous occurrence of charge-assisted aromatic and aliphatic C−H noncovalent interactions. PCM/DFT calculations have been carried out to predict the structures of the complexes formed with one and two molecules of PF , HPO and HPO . | Versión del editor: | http://dx.doi.org/10.1002/slct.201800809 | URI: | http://hdl.handle.net/10261/166545 | DOI: | 10.1002/slct.201800809 | Identificadores: | doi: 10.1002/slct.201800809 issn: 2365-6549 |
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