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Closed Access item Aminoselenenylation of alkenes: syntheses of β-phenylseleno carbamates and β-phenylseleno cyanamides

Authors:Francisco, Cosme G.
Hernández, Rosendo
León, Elisa I.
Salazar, José A.
Suárez, Ernesto
Issue Date:1990
Publisher:Royal Society of Chemistry (Great Britain)
Citation:Journal of the Chemical Society - Perkin Transactions 1990(9): 2417-2427 (1990)
Abstract:β-(Phenylseleno)alkylcarbamates and β-(phenylseleno)alkylcyanamides have been synthesized in good yields by reaction of alkenes with carbamates and cyanamide, respectively, in presence of benzeneselenenyl chloride–silver tetrafluoroborate or N-phenylselenophthalimide–H+. The subsequent reductive or oxidative removal of the phenylseleno group affords alkylcarbamates and alkylcyanamides, and allylic carbamates, cyanamides, and cyanimides.
Description:11 pages, 4 tables, 6 schemes.
Publisher version (URL):http://dx.doi.org/10.1039/P19900002417
URI:http://hdl.handle.net/10261/16428
ISSN:1472-7781
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Appears in Collections:(IPNA) Artículos

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