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Closed Access item Fragmentation of alkoxy radicals: Mechanistic aspects of the tandemβ-fragmentation-intramolecular functionalization reaction

Authors:Hernández, Rosendo
Marrero, José J.
Suárez, Ernesto
Perales, Áurea
Issue Date:1988
Publisher:Elsevier
Citation:Tetrahedron Letters 29(46): 5979-5981 (1988)
Abstract:The formation of the β-peroxylactone (4) during the photolysis of lactol (3) with (diacetoxyiodo)-benzene (DIB) and iodine under oxygen atmosphere demostrates the presence of a peroxyradical intermediate in the tandem β-fragmentation-intramolecular functionalization reaction.
Description:4 pages, 1 figure, 1 table, 1 scheme.
Publisher version (URL):http://dx.doi.org/10.1016/S0040-4039(00)82245-5
URI:http://hdl.handle.net/10261/16414
ISSN:0040-4039
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