Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/162716
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | From Allylic Sulfoxides to Allylic Sulfenates: Fifty Years of a Never-Ending [2,3]-Sigmatropic Rearrangement |
Autor: | Colomer, Ignacio CSIC ORCID ; Velado, Marina CSIC ORCID; Fernández de la Pradilla, Roberto CSIC ORCID; Viso, Alma CSIC ORCID | Fecha de publicación: | 2017 | Editor: | American Chemical Society | Citación: | Chemical Reviews 117: 14201-14243 (2017) | Resumen: | The [2,3]-sigmatropic rearrangement of allylic sulfoxides to allylic sulfenates is a reversible process, generally shifted toward the sulfoxide. In the presence of thiophiles, the sulfenate is trapped, and allylic alcohols are obtained under mild conditions. In most cases, a good transfer of stereochemical information through an ordered transition state is obtained. Furthermore, the ease of coupling this process with other versatile, stereocontrolled reactions has enhanced the usefulness of this protocol. This review aims to provide a comprehensive survey of this rearrangement and its application in the synthesis of natural and bioactive products. | Versión del editor: | http://dx.doi.org/10.1021/acs.chemrev.7b00428 | URI: | http://hdl.handle.net/10261/162716 | DOI: | 10.1021/acs.chemrev.7b00428 | Identificadores: | doi: 10.1021/acs.chemrev.7b00428 issn: 0009-2665 e-issn: 1520-6890 |
Aparece en las colecciones: | (IQOG) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
accesoRestringido.pdf | 15,38 kB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
SCOPUSTM
Citations
48
checked on 13-abr-2024
WEB OF SCIENCETM
Citations
48
checked on 25-feb-2024
Page view(s)
306
checked on 18-abr-2024
Download(s)
93
checked on 18-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
NOTA: Los ítems de Digital.CSIC están protegidos por copyright, con todos los derechos reservados, a menos que se indique lo contrario.