Por favor, use este identificador para citar o enlazar a este item:
http://hdl.handle.net/10261/155635
COMPARTIR / EXPORTAR:
SHARE CORE BASE | |
Visualizar otros formatos: MARC | Dublin Core | RDF | ORE | MODS | METS | DIDL | DATACITE | |
Título: | Metal-organic frameworks (MOFs) bring new life to hydrogen-bonding organocatalysts in confined spaces |
Autor: | Alegre-Requena, Juan V. CSIC ORCID; Marqués-López, Eugenia CSIC ORCID; Herrera, Raquel P. CSIC ORCID; Díaz Díaz, David CSIC ORCID | Fecha de publicación: | 2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | CrystEngComm 18(22): 3985-3995 (2016) | Resumen: | Hydrogen-bonding organocatalysis has emerged as a promising biomimetic alternative to Lewis acid catalysis. Urea, thiourea and squaramide moieties represent the most common hydrogen-bond donors used for the preparation of these catalysts. However, their significant tendency to undergo self-quenching (self-aggregation) often decreases their solubility and reactivity. Recently, scientists have found a promising way around this problem by immobilizing the hydrogen-bonding organocatalysts on metal-organic frameworks (MOFs). Along with advantageous modular synthesis and recycling properties, the tunable porosity and topology of MOFs also allows fast mass transport and/or interactions with substrates. Herein, we highlight the existing examples dealing with the fabrication and testing of hydrogen-bonding organocatalyst-containing MOFs, providing also our vision for further advances in this area. The results derived from these studies will likely serve as inspiration for the future development of superior hydrogen-bonding organocatalysts to accomplish in confined spaces chemical transformations that are either slow or unaffordable under standard homogeneous conditions. | Versión del editor: | https://doi.org/10.1039/C5CE02526E | URI: | http://hdl.handle.net/10261/155635 | DOI: | 10.1039/C5CE02526E | Identificadores: | doi: 10.1039/C5CE02526E e-issn: 1466-8033 |
Aparece en las colecciones: | (IQAC) Artículos (ISQCH) Artículos |
Ficheros en este ítem:
Fichero | Descripción | Tamaño | Formato | |
---|---|---|---|---|
MOFsbring.pdf | 4,75 MB | Adobe PDF | Visualizar/Abrir |
CORE Recommender
WEB OF SCIENCETM
Citations
52
checked on 14-feb-2024
Page view(s)
252
checked on 23-abr-2024
Download(s)
234
checked on 23-abr-2024
Google ScholarTM
Check
Altmetric
Altmetric
Este item está licenciado bajo una Licencia Creative Commons