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Title: Chemical polymerization of polyaniline and polypyrrole by phosphomolybdic acid : In situ formation of hybrid organic-inorganic materials
Authors: Gómez-Romero, P., Casañ Pastor, Nieves, Lira-Cantú, Monica
Keywords: Hybrid organic-inorganic compounds
Conducting polymers
Electrodes
Batteries
Issue Date: Nov-1997
Publisher: Elsevier
Abstract: The oxidative polymerization of aniline or pyrrole by phosphomolybdic acid (H3PMo12O40) is described. These reactions take place in the absence of other anions and result in the incorporation of the photoactive and electroactive PMo12O403− anion into the lattice of the polymer. The resulting hybrid materials present the good conductivity and polymeric nature of the matrix plus the added electroactivity of the inorganic cluster, which is anchored in the polymer and not exchanged upon reduction. The hybrids can work as electrodes harnessing the electrochemical properties of the polyoxometalic clusters
Description: International Symposium on the Reactivity of Solids. - Texto completo disponible en la web del autor: http://www.cienciateca.com/PAni_PPy_PMo12_Chem_SSI_97_101_875.pdf
Publisher version (URL): http://dx.doi.org/10.1016/S0167-2738(97)00222-1
URI: http://hdl.handle.net/10261/15550
ISSN: 0167-2738/
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Citation: Solid State Ionics 101-103: 875-880 (1997)
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