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Closed Access item Chemical polymerization of polyaniline and polypyrrole by phosphomolybdic acid : In situ formation of hybrid organic-inorganic materials

Authors:Gómez-Romero, P.
Casañ Pastor, Nieves
Lira-Cantú, Monica
Keywords:Hybrid organic-inorganic compounds, Conducting polymers, Electrodes, Batteries
Issue Date:Nov-1997
Citation:Solid State Ionics 101-103: 875-880 (1997)
Abstract:The oxidative polymerization of aniline or pyrrole by phosphomolybdic acid (H3PMo12O40) is described. These reactions take place in the absence of other anions and result in the incorporation of the photoactive and electroactive PMo12O403− anion into the lattice of the polymer. The resulting hybrid materials present the good conductivity and polymeric nature of the matrix plus the added electroactivity of the inorganic cluster, which is anchored in the polymer and not exchanged upon reduction. The hybrids can work as electrodes harnessing the electrochemical properties of the polyoxometalic clusters
Description:International Symposium on the Reactivity of Solids. - Texto completo disponible en la web del autor: http://www.cienciateca.com/PAni_PPy_PMo12_Chem_SSI_97_101_875.pdf
Publisher version (URL):http://dx.doi.org/10.1016/S0167-2738(97)00222-1
Appears in Collections:(ICMAB) Artículos

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