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Título : Electrochemical and Chemical Syntheses of the Hybrid Organic-Inorganic Electroactive Material formed by Phosphomolybdate and Polyaniline. Application as Cation-Insertion Electrodes
Autor : Lira-Cantú, Monica, Gómez-Romero, P.
Palabras clave : Cation-Insertion Electrodes
Electrochemical and Chemical Syntheses
Fecha de publicación : 18-Feb-1998
Editor: American Chemical Society
Resumen: We report a hybrid organic-inorganic electroactive material composed of a conducting polyaniline matrix and the phosphomolybdate anion ([PMo12O40]3-) as the active inorganic component. The material can be prepared electrochemically as thin films or chemically in the bulk, in the absence of other competing anions. The phosphomolybdate anion is anchored within the polymer matrix and not exchanged upon reduction. The material presents good conductivity and electroactivity, and it represents an example of electrodes that can take advantage of the electroactivity of zero-dimensional molecular species. A preliminary analysis of the material as a cathode in reversible lithium batteries is discussed
Descripción : Texto completo en la web del autor:
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ISSN: 0897-4756
DOI: 10.1021/cm970107u
Citación : Chemistry of materials 10: 698-704 (1998)
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