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Closed Access item Ag2Cu2O3 : The First Silver-Copper Oxide

Authors:Gómez-Romero, P.
Tejada Rosales, E. M.
Palacín, M. R.
Keywords:Oxygen, Superconductors, Copper, Silver, Solid-state structures
Issue Date:24-Feb-1999
Publisher:Wiley-VCH
Citation:Angewandte Chemie. International edition in English 38(4): 524-525 (1999)
Abstract:An efficient low-temperature route provides the first mixed oxide of silver and copper. Ag2Cu2O3 represents an important precedent in the search for silver-containing superconductors. It has an open structure with three-dimensional tunnels displaying square-planar CuO4 units, linerly coordinated silver ions, and vacant oxygen sites (see picture; Ag, Cu, and O are represented by white, large black, and small black spheres, respectively). The last feature allows for a rich solid-state redox chemistry.
Description:Texto completo disponible en la web del autor: http://www.cienciateca.com/Ag2Cu2O3_Angew_Chem_99_38_524.pdf
Publisher version (URL):http://dx.doi.org/10.1002/(SICI)1521-3773(19990215)38:4<524::AID-ANIE524>3.0.CO;2-F
URI:http://hdl.handle.net/10261/15473
ISSN:1521-3773 (Online)
1433-7851 (Print)
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Appears in Collections:(ICMAB) Artículos

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