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Título: | TTF–PTM dyads: from switched molecular self assembly in solution to radical conductors in solid state |
Autor: | Souto Salom, Manuel; Rovira, Concepció CSIC ORCID; Ratera, Immaculada; Veciana, Jaume CSIC ORCID CVN | Palabras clave: | Intramolecular electron-transfer Donor-acceptor systems Bond ground-state Charge delocalization Mixed-valence Organic radicals Room-temperature Building-blocks Pi-dimers Tetrathiafulvalene |
Fecha de publicación: | 14-ene-2017 | Editor: | Royal Society of Chemistry (UK) | Citación: | CrystEngComm 19(2): 197-206 (2017) | Resumen: | Organic donor-acceptor (D-A) systems formed by the electron-donor tetrathiafulvalene (TTF) linked to the electron-acceptor polychlorotriphenylmethyl (PTM) radical through different π-conjugated bridges exhibit interesting physical properties such as bistability in solution or conductivity in solid state. Understanding the interplay between intra- and intermolecular charge transfer processes in solution is of high interest in order to rationalize the self-assembling ability and conducting properties of such dyads in solid state. In this Highlight we go over the self-assembling properties of different TTF-π-PTM radical dyads that find potential applications as molecular switches or conductors in the field of molecular electronics. | Versión del editor: | http://dx.doi.org/10.1039/C6CE01660J | URI: | http://hdl.handle.net/10261/150991 | DOI: | 10.1039/C6CE01660J | ISSN: | 1466-8033 |
Aparece en las colecciones: | (ICMAB) Artículos |
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Souto_CrystEngComm_2017_postprint.pdf | 1,21 MB | Adobe PDF | Visualizar/Abrir |
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