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Título: | Confinement effect on ultrafast events of a salicylideneaniline derivative within mesoporous materials |
Autor: | Alarcos, Noemi; Sánchez, Félix CSIC ORCID; Douhal, Abderrazzak | Palabras clave: | Silica-based materials Metal doping effect H- and J-aggregates dynamics Femtosecond spectroscopy Mesoporous materials |
Fecha de publicación: | 2017 | Editor: | Elsevier | Citación: | Microporous and Mesoporous Materials 248: 54-61 (2017) | Resumen: | We report on femtosecond (fs) studies of HBA-4NP interacting with MCM41, Al-MCM41 and SBA15 materials, and discuss the dynamics of caged monomers and J-aggregates. For MCM41 and Al-MCM41 composites, and upon excitation at 380 nm (monomers region) the ultrafast dynamics (250 fs and 2.5 ps for HBA-4NP/MCM41, 350 fs and 3.5 ps for HBA-4NP/Al-MCM41) is slower than that observed in solution due to aggregates formation inside the material pores. While exciting at 410 nm, we got a slower behaviour. However, for HBA-4NP/SBA15 composites, with a low loading, where the caged monomers are the main guests, we recorded faster dynamics (200 fs and 2 ps) independently on the pumping wavelength. These results show how the properties of mesoporous materials, especially its pore size and Al-doping, affect the nature of the formed composites and their ultrafast photodynamics. | Descripción: | Supplementary data related to this article can be found at http:// dx.doi.org/10.1016/j.micromeso.2017.04.011. | Versión del editor: | http://dx.doi.org/10.1016/j.micromeso.2017.04.011 | URI: | http://hdl.handle.net/10261/149576 | DOI: | 10.1016/j.micromeso.2017.04.011 | Identificadores: | doi: 10.1016/j.micromeso.2017.04.011 issn: 1387-1811 |
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