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Título: | A redox-active radical as an effective nanoelectronic component: stability and electrochemical tunnelling spectroscopy in ionic liquids |
Autor: | Rudnev, Alexander V.; Franco, Carlos CSIC ORCID; Crivillers, Núria CSIC ORCID; Seber, Gonca CSIC ORCID; Droghetti, Andrea CSIC ORCID CVN; Rungger, Ivan; Pobelov, Ilya V.; Veciana, Jaume CSIC ORCID CVN; Mas Torrent, Marta CSIC ORCID; Rovira, Concepció CSIC ORCID | Palabras clave: | Single-molecule electronics Break junction Transistor Voltammetry Conductance Ferrocene |
Fecha de publicación: | 28-oct-2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | Physical Chemistry Chemical Physics 18(40): 27733-27737 (2016) | Resumen: | A redox-active persistent perchlorotriphenylmethyl (PTM) radical chemically linked to gold exhibits stable electrochemical activity in ionic liquids. Electrochemical tunnelling spectroscopy in this medium demonstrates that the PTM radical shows a highly effective redox-mediated current enhancement, demonstrating its applicability as an active nanometer-scale electronic component. | Versión del editor: | http://dx.doi.org/10.1039/C6CP05658J | URI: | http://hdl.handle.net/10261/148760 | DOI: | 10.1039/C6CP05658J | ISSN: | 1463-9076 |
Aparece en las colecciones: | (ICMAB) Artículos (CFM) Artículos |
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Rudnev_PCCP_2016_editorial.pdf | Artículo principal | 2,12 MB | Adobe PDF | Visualizar/Abrir |
Rudnev_PCCP_2016_suppl_editorial.pdf | Información suplementaria | 1,87 MB | Adobe PDF | Visualizar/Abrir |
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