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Título: | A symmetric, triply interlaced 3-D anionic MOF that exhibits both magnetic order and SMM behaviour |
Autor: | Campo, Javier CSIC ORCID ; Falvello, Larry R. CSIC ORCID; Forcén-Vázquez, E. CSIC ORCID; Sáenz de Pipaón, C.; Palacio, Fernando CSIC ORCID; Tomás, Milagros CSIC ORCID | Fecha de publicación: | 2016 | Editor: | Royal Society of Chemistry (UK) | Citación: | Dalton Transactions 45(42): 16764-16768 (2016) | Resumen: | A newly prepared 3-D polymer of cobalt citrate cubanes bridged by high-spin Co(ii) centres displays both single-molecule magnet (SMM) behaviour and magnetic ordering. Triple interpenetration of the 3-D diamondoid polymers yields a crystalline solid with channels that host cations and free water molecules, with the SMM behaviour of the CoO cores preserved. The octahedrally coordinated Co(ii) bridges are implicated in the onset of magnetic order at an experimentally accessible temperature. | Versión del editor: | https://doi.org/10.1039/c6dt02652d | URI: | http://hdl.handle.net/10261/148597 | DOI: | 10.1039/c6dt02652d | Identificadores: | doi: 10.1039/c6dt02652d e-issn: 1477-9234 issn: 1477-9226 |
Aparece en las colecciones: | (ISQCH) Artículos (ICMA) Artículos |
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SMM behaviour.pdf | 2,39 MB | Adobe PDF | Visualizar/Abrir |
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