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Por favor, use este identificador para citar o enlazar a este item: http://hdl.handle.net/10261/148549
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dc.contributor.authorBadetti, Elenaes_ES
dc.contributor.authorLloveras, Vegaes_ES
dc.contributor.authorRomano, Francescoes_ES
dc.contributor.authorLorenzo, Rosalia Dies_ES
dc.contributor.authorVeciana, Jaumees_ES
dc.contributor.authorVidal Gancedo, Josées_ES
dc.contributor.authorZonta, Cristianoes_ES
dc.contributor.authorLicini, Giuliaes_ES
dc.date.accessioned2017-04-20T08:30:50Z-
dc.date.available2017-04-20T08:30:50Z-
dc.date.issued2016-11-
dc.identifier.citationEuropean Journal of Inorganic Chemistry (31): 4968–4973 (2016)es_ES
dc.identifier.issn1434-1948-
dc.identifier.urihttp://hdl.handle.net/10261/148549-
dc.description.abstractA new stable radical-containing ligand and the corresponding VV, TiIV, and MoVI complexes have been synthesized and studied by electron paramagnetic resonance (EPR) spectroscopy. To achieve this goal, a novel strategy for the post-derivatization of a triphenolamine (TPA) ligand has been developed. This has allowed the effective embedding of three TEMPO (2,2,6,6-tetramethyl-1-piperidinyloxy) radicals in the corresponding metal complexes. In these systems, dipolar interactions among the organic radicals are strongly dependent on the geometry assumed in solution: a |Δms| = 2 transition is observed when the geometry of the complexes is octahedral, whereas no signal is detected with trigonal bipyramidal geometries.es_ES
dc.description.sponsorshipThis research was supported by the Università di Padova, Italy(grant numbers PRAT-CPDA123307 and CPDA153122, Attrezza-ture Scientifiche Finalizzate Alla Ricerca 2014) and the ItalianMinistero dell'Università e della Ricerca (MIUR) (PRIN-2010-112010CX2TLM_002, E. B. fellowship). This work was carried outwithib the framework of the COST Action CM1205, CatalyticRoutines for Small Molecules Activation (CARISMA). The SpanishDirección General de Investigación (BeWell Grant numberCTQ2013-40480-R) and L'Agència de G estió d'Ajuts Universitarisi de Recerca (AGAUR) (grant number 2014-SGR-17) are also ac-knowledged. CIBER-BBN is an initiative funded by the VI Na-tional R&D&i Plan 2008–2011, Iniciativa Ingenio 2010, Consol-ider Program, CIBER Actions and financed by the Instituto deSalud Carlos III with assistance from the European Regional De-velopment Fund.es_ES
dc.language.isoenges_ES
dc.publisherWiley-VCHes_ES
dc.relationinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013-40480-Res_ES
dc.relation.isversionofPostprintes_ES
dc.rightsopenAccessen_EN
dc.subjectVanadiumes_ES
dc.subjectMolybdenumes_ES
dc.subjectTitaniumes_ES
dc.subjectRadicalses_ES
dc.subjectEPR spectroscopyes_ES
dc.titleDiscrimination of Octahedral versus Trigonal Bipyramidal Coordination Geometries of Homogeneous TiIV, VV, and MoVI Amino Triphenolate Complexes through Nitroxyl Radical Unitses_ES
dc.typeartículoes_ES
dc.identifier.doi10.1002/ejic.201600649-
dc.description.peerreviewedPeer reviewedes_ES
dc.relation.publisherversionhttp://dx.doi.org/10.1002/ejic.201600649es_ES
dc.embargo.terms2017-11-30es_ES
dc.contributor.funderUniversità degli Studi di Padovaes_ES
dc.contributor.funderMinistero dell'Istruzione, dell'Università e della Ricercaes_ES
dc.contributor.funderEuropean Cooperation in Science and Technologyes_ES
dc.contributor.funderMinisterio de Economía y Competitividad (España)es_ES
dc.contributor.funderGeneralitat de Catalunyaes_ES
dc.contributor.funderCentro de Investigación Biomédica en Red Bioingeniería, Biomateriales y Nanomedicina (España)es_ES
dc.contributor.funderInstituto de Salud Carlos IIIes_ES
dc.relation.csicSíes_ES
oprm.item.hasRevisionno ko 0 false*
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003500es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003407es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100000921es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100003329es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100002809es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100005053es_ES
dc.identifier.funderhttp://dx.doi.org/10.13039/501100004587es_ES
dc.type.coarhttp://purl.org/coar/resource_type/c_6501es_ES
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item.cerifentitytypePublications-
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item.languageiso639-1en-
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